4-Chloro-N-(3,5-dichloro­phen­yl)-2-methyl­benzene­sulfonamide

نویسندگان

  • Vinola Z. Rodrigues
  • Sabine Foro
  • B. Thimme Gowda
  • K. Shakuntala
چکیده

In the title compound, C(13)H(10)Cl(3)NO(2)S, torsion angle of the C-SO(2)-NH-C group in the mol-ecule is -58.57 (26)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 84.2 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.

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N-(3,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide

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4-Chloro-N-(2,3-dichloro­phen­yl)-2-methyl­benzene­sulfonamide

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In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of 64.3 (4)°. Furthermore, the conformation of the N-H bond and the meta-chloro group in the adjacent benzene ring are anti to each other. The two benzene rings are tilt...

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N-(2,5-Dichloro­phen­yl)-4-methyl­benzene­sulfonamide

In the title compound, C(13)H(11)Cl(2)NO(2)S, the N-C bond in the C-SO(2)-NH-C segment has gauche torsion angles with respect to the S=O bonds. The mol-ecule is bent at the S atom with an C-SO(2)-NH-C torsion angle of 62.1 (2)°. Furthermore, the conformation of the N-H bond is syn to the ortho-chloro group in the adjacent benzene ring. The benzene rings are tilted by 67.8 (1)° relative to each ...

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The structure of the title compound, C(8)H(6)Cl(3)NO, is closely related to that of N-(3,5-dichloro-phen-yl)acetamide and other amides. The mol-ecular skeleton is essentially planar. The mol-ecules in the crystal structure are stabilized by N-H⋯O and N-H⋯Cl inter-molecular hydrogen bonds running along the a axis.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011